Pre-heat the oven to 325° F.
Line the bottoms of three, 9-inch cake pans with parchment paper. To do so, trace the bottom of the pan on a piece of parchment paper; cut out the circle. Spray the pans with a butter spray and lightly flour.
In a large bowl, sift together cake flour, baking powder, baking soda, salt, and white vanilla powder. Set aside.
In a large bowl, whisk together milk, sour cream, and white vinegar. Set aside.
Using a stand-mixer with the paddle attachment, cream together the butter and sugar on low speed, until light and fluffy. Scrape down the bowl, as needed.
On low speed, add the egg whites, approximately one at a time. Mix until the egg whites are incorporated. Scrape down the bowl as needed.
Add the flour and the milk/sour cream mixtures to the butter, sugar, and egg white mixture, alternating between batches. Start with approximately a third of the flour mixture, then add a third of the milk/sour cream mixture. Repeat and end with the flour mixture. Scrape down the bowl, as needed. Mix until just incorporated, try not to over mix.
Divide the batter evenly between the three prepared 9-inch cake pans. Bake at 325° F, approximately 45-55 minutes. After about 40 minutes, check the cakes with a toothpick; remove cakes from the oven when it comes out clean.
Place the cakes on cooling racks. Leave the cakes in the pans to cool, until almost cooled completely!
Once cakes are almost completely cooled, flip over onto the cooling rack; remove from the pans. Peel off the parchment paper and leave cakes on the rack to cool completely.
Wrap each cake in plastic wrap and refrigerate until chilled, at least one hour, prior to frosting. (The cakes may also be wrapped and frozen, if they will not be frosted within a few days to a week.)